Silver Thimbles. Thimbles are usually made from metal, leather, rubber, and wood, and even glass or china. Early thimbles were sometimes made from whale bone, horn, or ivory. Natural sources were also utilized such as Connemara marble, bog oak, or mother of pearl. Rarer works from thimble makers utilized diamonds, sapphires, or rubies.
Advanced thimble makers enhanced thimbles with semi-precious stones to adorn the apex or along the outer rim. Cabochon adornments are sometimes made of cinnabar, agate, moonstone, or amber. Thimble artists would also utilize enameling, or the Guilloché techniques advanced by Peter Carl Fabergé.
In the 19th century, many thimbles were made from silver; however, it was found that silver is too soft a metal and can be easily punctured by most needles.
Charles Horner solved the problem by creating thimbles consisting of a steel core covered inside and out by silver, so that they retained their aesthetics but were now more practical and durable. He called his thimble the Dorcas, and these are now popular with collectors. There is a small display of his work in Bankfield Museum, Halifax, England. Reference: Wikipedia
Below are some examples of silver thimbles which have been used throughout history.